All Faculty and Research Staff Publications

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Kozack CV, Sowin JA, Jaworski JN, Iosub AV, Stahl SS. Aerobic Acyloxylation of Allylic C-H Bonds Initiated by a Pd-0 Precatalyst with 4,5-Diazafluoren-9-one as an Ancillary Ligand. Chemsuschem. 2019 ;12:3003-3007.
Wang YH, Schneider PE, Goldsmith ZK, Mondal B, Hammes-Schiffer S, Stahl SS. Bronsted Acid Scaling Relationships Enable Control Over Product Selectivity from O-2 Reduction with a Mononuclear Cobalt Porphyrin Catalyst. ACS Central Science. 2019 ;5:1024-1034.
Ryan MC, Whitmire LD, McCann SD, Stahl SS. Copper/TEMPO Redox Redux: Analysis of PCET Oxidation of TEMPOH by Copper(II) and the Reaction of TEMPO with Copper(I). Inorganic Chemistry. 2019 ;58:10194-10200.
Das A, Nutting JE, Stahl SS. Electrochemical C-H oxygenation and alcohol dehydrogenation involving Fe-oxo species using water as the oxygen source. Chemical Science. 2019 ;10:7542-7548.
Perez JM, Kontur WS, Alherech M, Coplien J, Karlen SD, Stahl SS, Donohue TJ, Noguera DR. Funneling aromatic products of chemically depolymerized lignin into 2-pyrone-4-6-dicarboxylic acid with Novosphingobium aromaticivorans. Green Chemistry. 2019 ;21:1340-1350.
Singh SK, Savoy AW, Yuan ZY, Luo H, Stahl SS, Hegg EL, Hodge DB. Integrated Two-Stage Alkaline-Oxidative Pretreatment of Hybrid Poplar. Part 1: Impact of Alkaline Pre-Extraction Conditions on Process Performance and Lignin Properties. Industrial & Engineering Chemistry Research. 2019 ;58:15989-15999.
Wang F, Stahl SS. Merging Photochemistry with Electrochemistry: Functional-Group Tolerant Electrochemical Amination of C(sp(3))-H Bonds. Angewandte Chemie-International Edition. 2019 ;58:6385-6390.
Jaworski JN, Kozack CV, Tereniak SJ, Knapp SMM, Landis CR, Miller JT, Stahl SS. Operando Spectroscopic and Kinetic Characterization of Aerobic Allylic C-H Acetoxylation Catalyzed by Pd(OAc)(2)/4,5-Diazafluoren-9-one. Journal of the American Chemical Society. 2019 ;141:10462-10474.
Piszel PE, Vasilopoulos A, Stahl SS. Oxidative Amide Coupling from Functionally Diverse Alcohols and Amines Using Aerobic Copper/Nitroxyl Catalysis. Angewandte Chemie-International Edition. 2019 .
Beller M, Shi F, Stahl SS. Preface to Special Issue of ChemSusChem: Sustainable Organic Synthesis. Chemsuschem. 2019 ;12:2834-2834.
Li B, Wendlandt AE, Stahl SS. Replacement of Stoichiometric DDQ with a Low Potential o-Quinone Catalyst Enabling Aerobic Dehydrogenation of Tertiary Indolines in Pharmaceutical Intermediates. Organic Letters. 2019 ;21:1176-1181.
Tereniak SJ, Landis CR, Stahl SS. Are Phosphines Viable Ligands for Pd-Catalyzed Aerobic Oxidation Reactions? Contrasting Insights from a Survey of Six Reactions. Acs Catalysis. 2018 ;8:3708-3714.
Ryan MC, Martinelli JR, Stahl SS. Cu-Catalyzed Aerobic Oxidative N-N Coupling of Carbazoles and Diarylamines Including Selective Cross-Coupling. Journal of the American Chemical Society. 2018 ;140:9074-9077.
Lennox AJJ, Goes SL, Webster MP, Koolman HF, Djuric SW, Stahl SS. Electrochemical Aminoxyl-Mediated alpha-Cyanation of Secondary Piperidines for Pharmaceutical Building Block Diversification. Journal of the American Chemical Society. 2018 ;140:11227-11231.
Wang F, Rafiee M, Stahl SS. Electrochemical Functional-Group-Tolerant Shono-type Oxidation of Cyclic Carbamates Enabled by Aminoxyl Mediators. Angewandte Chemie-International Edition. 2018 ;57:6686-6690.
Rafiee M, Konz ZM, Graaf MD, Koolman HF, Stahl SS. Electrochemical Oxidation of Alcohols and Aldehydes to Carboxylic Acids Catalyzed by 4-Acetamido-TEMPO: An Alternative to "Anelli" and "Pinnick" Oxidations. Acs Catalysis. 2018 ;8:6738-6744.
Wang YH, Goldsmith ZK, Schneider PE, Anson CW, Gerken JB, Ghosh S, Hammes-Schiffer S, Stahl SS. Kinetic and Mechanistic Characterization of Low-Overpotential, H2O2-Selective Reduction of O-2 Catalyzed by N2O2-Ligated Cobalt Complexes. Journal of the American Chemical Society. 2018 ;140:10890-10899.
Wang D, Weinstein AB, White PB, Stahl SS. Ligand-Promoted Palladium-Catalyzed Aerobic Oxidation Reactions. Chemical Reviews. 2018 ;118:2636-2679.
Das A, Rahimi A, Ulbrich A, Alherech M, Motagamwala AH, Bhalla A, Sousa LD, Balan V, Dumesic JA, Hegg EL, et al. Lignin Conversion to Low-Molecular-Weight Aromatics via an Aerobic Oxidation-Hydrolysis Sequence: Comparison of Different Lignin Sources. Acs Sustainable Chemistry & Engineering. 2018 ;6:3367-3374.
Mannel DS, King J, Preger Y, Ahmed MS, Root TW, Stahl SS. Mechanistic Insights into Aerobic Oxidative Methyl Esterification of Primary Alcohols with Heterogeneous PdBiTe Catalystsy. Acs Catalysis. 2018 ;8:1038-1047.
Rafiee M, Wang F, Hruszkewycz DP, Stahl SS. N-Hydroxyphthalimide-Mediated Electrochemical Iodination of Methylarenes and Comparison to Electron-Transfer-Initiated C-H Functionalization. Journal of the American Chemical Society. 2018 ;140:22-25.
Preger Y, Root TW, Stahl SS. Platinum-Based Heterogeneous Catalysts for Nitrile Synthesis via Aerobic Oxidative Coupling of Alcohols and Ammonia. Acs Omega. 2018 ;3:6091-6096.
Lennox AJJ, Nutting JE, Stahl SS. Selective electrochemical generation of benzylic radicals enabled by ferrocene-based electron-transfer mediators. Chemical Science. 2018 ;9:356-361.
Gerken JB, Pang YTQ, Lauber MB, Stahl SS. Structural Effects on the pH-Dependent Redox Properties of Organic Nitroxyls: Pourbaix Diagrams for TEMPO, ABNO, and Three TEMPO Analogs. Journal of Organic Chemistry. 2018 ;83:7323-7330.
Nutting JE, Rafiee M, Stahl SS. Tetramethylpiperidine N-Oxyl (TEMPO), Phthalimide N-Oxyl (PINO), and Related N-Oxyl Species: Electrochemical Properties and Their Use in Electrocatalytic Reactions. Chemical Reviews. 2018 ;118:4834-4885.
Ahmed MS, Mannel DS, Root TW, Stahl SS. Aerobic Oxidation of Diverse Primary Alcohols to Carboxylic Acids with a Heterogeneous Pd-Bi-Te/C (PBT/C) Catalyst. Org. Process Res. Dev. 2017 ;21:1388-1393.
Goldsmith ZK, Harshan AK, Gerken JB, Voros M, Galli G, Stahl SS, Hammes-Schiffer S. Characterization of NiFe oxyhydroxide electrocatalysts by integrated electronic structure calculations and spectroelectrochemistry. Proceedings of the National Academy of Sciences of the United States of America. 2017 ;114:3050-3055.
Stahl SS, Rovis T. Cluster Preface: Catalytic Aerobic Oxidations. Synlett. 2017 ;28:1546-1547.
Hruszkewycz DP, Miles KC, Thiel OR, Stahl SS. Co/NHPI-mediated aerobic oxygenation of benzylic C-H bonds in pharmaceutically relevant molecules. Chemical Science. 2017 ;8:1282-1287.
Anson CW, Stahl SS. Cooperative Electrocatalytic O-2 Reduction Involving Co(salophen) with p-Hydroquinone as an Electron-Proton Transfer Mediator. Journal of the American Chemical Society. 2017 ;139:18472-18475.
Jaworski JN, McCann SD, Guzei IA, Stahl SS. Detection of Palladium(I) in Aerobic Oxidation Catalysis. Angewandte Chemie-International Edition. 2017 ;56:3605-3610.
Mannel DS, Ahmed MS, Root TW, Stahl SS. Discovery of Multicomponent Heterogeneous Catalysts via Admixture Screening: PdBiTe Catalysts for Aerobic Oxidative Esterification of Primary Alcohols. Journal of the American Chemical Society. 2017 ;139:1690-1698.
Walroth RC, Miles KC, Lukens JT, MacMillan SN, Stahl SS, Lancaster KM. Electronic Structural Analysis of Copper(II)-TEMPO/ABNO Complexes Provides Evidence for Copper(I)-Oxoammonium Character. Journal of the American Chemical Society. 2017 ;139:13507-13517.
Vasilopoulos A, Zultanski SL, Stahl SS. Feedstocks to Pharmacophores: Cu-Catalyzed Oxidative Arylation of Inexpensive Alkylarenes Enabling Direct Access to Diarylalkanes. Journal of the American Chemical Society. 2017 ;139:7705-7708.
Tereniak SJ, Stahl SS. Mechanistic Basis for Efficient, Site-Selective, Aerobic Catalytic Turnover in Pd-Catalyzed C-H Imidoylation of Heterocycle-Containing Molecules. Journal of the American Chemical Society. 2017 ;139:14533-14541.
Wang YH, Pegis ML, Mayer JM, Stahl SS. Molecular Cobalt Catalysts for O-2 Reduction: Low-Overpotential Production of H2O2 and Comparison with Iron-Based Catalysts. Journal of the American Chemical Society. 2017 ;139:16458-16461.
Das A, Stahl SS. Noncovalent Immobilization of Molecular Electrocatalysts for Chemical Synthesis: Efficient Electrochemical Alcohol Oxidation with a Pyrene-TEMPO Conjugate. Angewandte Chemie-International Edition. 2017 ;56:8892-8897.
Wang DA, Stahl SS. Pd-Catalyzed Aerobic Oxidative Biaryl Coupling: Non-Redox Cocatalysis by Cu(OTf)(2) and Discovery of Fe(OTf)(3) as a Highly Effective Cocatalyst. Journal of the American Chemical Society. 2017 ;139:5704-5707.
McCann SD, Lumb JP, Arndtsen BA, Stahl SS. Second-Order Biomimicry: In Situ Oxidative Self-Processing Converts Copper(I)/Diannine Precursor into a Highly Active Aerobic Oxidation Catalyst. Acs Central Science. 2017 ;3:314-321.
Badalyan A, Stahl SS. Cooperative electrocatalytic alcohol oxidation with electron-proton-transfer mediators. Nature. 2016 ;535:406-410.
Anson CW, Ghosh S, Hammes-Schiffer S, Stahl SS. Co(salophen)-Catalyzed Aerobic Oxidation of p-Hydroquinone: Mechanism and Implications for Aerobic Oxidation Catalysis. Journal of the American Chemical Society. 2016 ;138:4186-4193.
White PB, Jaworski JN, Zhu GHarry, Stahl SS. Diazafluorenone-Promoted Oxidation Catalysis: Insights into the Role of Bidentate Ligands in Pd-Catalyzed Aerobic Aza-Wacker Reactions. Acs Catalysis. 2016 ;6:3340-3348.
Shaner SE, Hooker PD, Nickel AM, Leichtfuss AR, Adams CS, de la Cerda D, She YQ, Gerken JB, Pokhrel R, Ambrose NJ, et al. Discovering Inexpensive, Effective Catalysts for Solar Energy Conversion: An Authentic Research Laboratory Experience. Journal of Chemical Education. 2016 ;93:650-657.
Miles KC, Abrams ML, Landis CR, Stahl SS. KetoABNO/NOx Cocatalytic Aerobic Oxidation of Aldehydes to Carboxylic Acids and Access to alpha-Chiral Carboxylic Acids via Sequential Asymmetric Hydroformylation/Oxidation. Organic Letters. 2016 ;18:3590-3593.
McCann SD, Stahl SS. Mechanism of Copper/Azodicarboxylate-Catalyzed Aerobic Alcohol Oxidation: Evidence for Uncooperative Catalysis. Journal of the American Chemical Society. 2016 ;138:199-206.
Iosub AV, Stahl SS. Palladium-Catalyzed Aerobic Dehydrogenation of Cyclic Hydrocarbons for the Synthesis of Substituted Aromatics and Other Unsaturated Products. Acs Catalysis. 2016 ;6:8201-8213.
Zultanski SL, Zhao JY, Stahl SS. Practical Synthesis of Amides via Copper/ABNO-Catalyzed Aerobic Oxidative Coupling of Alcohols and Amines. Journal of the American Chemical Society. 2016 ;138:6416-6419.
Huynh MT, Anson CW, Cavell AC, Stahl SS, Hammes-Schiffer S. Quinone 1 e(-) and 2 e(-)/2 H+ Reduction Potentials: Identification and Analysis of Deviations from Systematic Scaling Relationships. Journal of the American Chemical Society. 2016 ;138:15903-15910.
White PB, Jaworski JN, Fry CG, Dolinar BS, Guzei IA, Stahl SS. Structurally Diverse Diazafluorene-Ligated Palladium(II) Complexes and Their Implications for Aerobic Oxidation Reactions. Journal of the American Chemical Society. 2016 ;138:4869-4880.
Clagg K, Hou HY, Weinstein AB, Russell D, Stahl SS, Koenig SG. Synthesis of Indole-2-carboxylate Derivatives via Palladium-Catalyzed Aerobic Amination of Aryl C-H Bonds. Organic Letters. 2016 ;18:3586-3589.